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M. L. NIU, E. J. SALUMBIDES, D. ZHAO, J. BAGDONAITE, Department of Physics and Astronomy, and LaserLaB, VU University, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands; N. DE OLIVEIRA, D. JOYEUX, L. NAHON, Synchrotron Soleil, Orme des Merisiers, St Aubin BP 48, 91192, GIF sur Yvette cedex, France; R. W. FIELD, Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA; AND W. UBACHS, Department of Physics and Astronomy, and LaserLaB, VU University, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands.
The \textrmA1
-\textrmX1
+ band system of carbon monoxide, which has been detected in six highly redshifted galaxies (z=1.6-2.7), is identified as a novel probe method to search for possible variations of the proton-electron mass ratio (µ) on cosmological time scales. Laboratory wavelengths of the spectral lines of the A-X (v,0) bands for v=0-9 have been determined at an accuracy of
/
=1.5 × 10-7 through VUV Fourier-transform absorption spectroscopy, providing a comprehensive and accurate zero-redshift data set. Two-photon Doppler-free laser spectroscopy has been applied for the (0,0) and (1,0) bands, achieving 3 × 10-8 accuracy level, verifying the absorption data. Accurate sensitivity coefficients Kµ for a varying µ have been calculated for the CO A-X bands, so that an operational method results to search for µ-variation. The data from both experiments were used to perform an improved analysis of the perturbations in the A1
, v=0 and 1 levels by vibrational levels in the D1
, I1
-, e3
-, d3
, and a'3
+ states. The object Q1237+064 will be observed in May 2013, aiming for a good signal-to-noise spectrum containing the CO A-X bands as well as the H2 Lyman and Werner bands. This should result in an accurate and robust constraint on
µ/µ.