TH. MICROWAVE

TUESDAY, JUNE 18, 2013 - 1:30PM

Room: 1000 MCPHERSON LAB

Chair: GILLES ADANDE, University of Arizona, Tucson, AZ

TH01 15min1:30

THE SUB-MILLIMETER WAVE SPECTROSCOPY OF MONODUTERATED AMIDOGEN RADICAL (NHD).

YUTA MOTOKI, HIROYUKI OZEKI, Department of Environmental Science, Toho University, 2-2-1 Miyama, Funabashi, 274-8510, Japan; KAORI KOBAYASHI, Department of Physics, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH02			15min1:47

FOURIER TRANSFORM MICROWAVE SPECTRUM OF N₂-(CH₂)₂O.

YOSHIYUKI KAWASHIMA, Department of Applied Chemistry, Faculty of Engineering, Kanagawa Institute of Technology, Atsugi, Kanagawa 243-0292, JAPAN; EIZI HIROTA, The Graduate University for Advanced Studies, Hayama, Kanagawa 240-0193, JAPAN.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH03			15min2:04

THE BROADBAND ROTATIONAL SPECTRUM AND GEOMETRY OF N₂ cdots

ICF₃.

N. R. WALKER, D. HIRD, School of Chemistry, Bedson Building, Newcastle University, Newcastle-upon-Tyne, NE1 7RU, U.K.; A. C. LEGON, School of Chemistry, University of Bristol, Bristol, BS8 1TS, U.K..

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

TH04			15min2:21

UNEXPECTED GENERATION AND OBSERVATION OF A T-SHAPED COMPLEX OF H₂C₂ cdots

AgCCH.

N. R. WALKER, School of Chemistry, Bedson Building, Newcastle University, Newcastle-upon-Tyne, NE1 7RU, U.K.; S. L. STEPHENS, W. MIZUKAMI, D. P. TEW AND A. C. LEGON, School of Chemistry, University of Bristol, Bristol, BS8 1TS, U.K..

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

TH05			15min2:38

STRUCTURES OF THE CAGE, PRISM, AND BOOK HEXAMER WATER CLUSTERS FROM MULTIPLE ISOTOPIC SUBSTITUTION.

SIMON LOBSIGER, CRISTOBAL PEREZ, DANIEL P. ZALESKI, NATHAN SEIFERT, BROOKS H. PATE, Department of Chemistry, University of Virginia, McCormick Rd., Charlottesville, VA 22904-4319; ZBIGNIEW KISIEL, Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland; BERHANE TEMELSO, GEORGE C. SHIELDS, Dean's Office, College of Arts and Sciences, and Department of Chemistry, Bucknell University, Lewisburg, PA 17837.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

TH06			15min2:55

CHARACTERIZATION OF LARGE WATER CLUSTERS BY BROADBAND ROTATIONAL SPECTROSCOPY.

CRISTOBAL PEREZ, DANIEL P. ZALESKI, NATHAN A. SEIFERT, BROOKS H. PATE, Department of Chemistry, University of Virginia, McCormick Rd., Charlottesville, VA 22904-4319; ZBIGNIEW KISIEL, Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland; BERHANE TEMELSO, GEORGE C. SHIELDS, Dean's Office, College of Arts and Sciences, and Department of Chemistry, Bucknell University, Lewisburg, PA 17837; STEVEN T. SHIPMAN, IAN FINNERMAN, Division of Natural Sciences, New College of Florida, Sarasota, FL 34243.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH07			15min3:12

HYDROGEN BOND NETWORK ISOMERS OF THE WATER NONAMER AND DECAMER OBSERVED BY BROADBAND ROTATIONAL SPECTROSCOPY.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH08			15min3:29

STRUCTURES OF THE LOWEST ENERGY NONAMER AND DECAMER WATER CLUSTERS FROM CHIRPED-PULSE ROTATIONAL SPECTROSCOPY.

CRISTOBAL PEREZ, BROOKS H. PATE, Department of Chemistry, University of Virginia, McCormick Rd., Charlottesville, VA 22904-4319; ZBIGNIEW KISIEL, Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland; BERHANE TEMELSO, GEORGE C. SHIELDS, Dean's Office, College of Arts and Sciences, and Department of Chemistry, Bucknell University, Lewisburg, PA 17837.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

INTERMISSION

TH09			15min4:00

MILLIMETER WAVE SPECTRA OF THE INTERNAL ROTATION EXCITED STATES OF (o)H₂-H₂O AND (o)H₂-D₂O.

K. HARADA, Y. IWASAKI, T. GIESEN AND K. TANAKA, Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashiku, Fukuoka, 812-8581 JAPAN.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH10			15min4:17

THE PERFORMANCE OF THE THIRD GENERATION OF CP-FTMW SPECTROMETERS ILLUSTRATED BY THE ANALYSIS OF THE WATER HEPTAMER STRUCTURE.

CRISTOBAL PEREZ, DANIEL P. ZALESKI, NATHAN A. SEIFERT, SIMON LOBSIGER, BROOKS H. PATE, Department of Chemistry, University of Virginia, McCormick Rd., Charlottesville, VA 22904-4319; ZBIGNIEW KISIEL, Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland; BERHANE TEMELSO, GEORGE C. SHIELDS, Dean's Office, College of Arts and Sciences, and Department of Chemistry, Bucknell University, Lewisburg, PA 17837; STEVEN T. SHIPMAN, Division of Natural Sciences, New College of Florida, Sarasota, FL 34243; DAVID W. PRATT, Department of Chemistry, The University of Vermont, Cook Physical Sciences Building, 82 University Place, Burlington, VT 05405.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH11			10min4:34

THE CYTOSINE WATER COMPLEX.

A. M. DALY, S. MATA, C. BERMUDEZ, M. BERDAKIN, I. PENA, C. CABEZAS, J. L. ALONSO, Grupo de Espectroscopía Molecular (GEM), Edificio Quifima, Laboratorios de Espectroscopía y Bioespectroscopía, Parque Científico, Universidad de Valladolid, 47011 Valladolid, Spain.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH12			10min4:46

EXPERIMENTAL~EVIDENCE~OF~LONE~PAIRS~-~

SYSTEM~INTERACTION: ~THE~ROTATIONAL~SPECTRUM~OF~CHLOROTRIFLUOROETHYLENE~-~WATER~COMPLEX.

L. EVANGELISTI, Q. GOU, G. FENG AND W. CAMINATI, Dipartimento di Chimica "G. Ciamician" dell'Universitá, Via Selmi 2, I-40126 Bologna, Italy.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH13			15min4:58

MICROWAVE SPECTRA AND STRUCTURE OF H₂--CuF: OVERVIEW OF THE COMPLEXES OF HYDROGEN WITH METAL-CONTAINING DIATOMICS.

G. S. GRUBBS II, DANIEL J. FROHMAN, Department of Chemistry, Wesleyan University, 52 Lawn Avenue, Middletown, CT, 06459-0180, USA; ZHENHONG YU, Aerodyne Research, Inc. 45 Manning Road, Billerica, MA 01821; STEWART E. NOVICK, Department of Chemistry, Wesleyan University, 52 Lawn Avenue, Middletown, CT, 06459-0180, USA (email to SEN: snovick@wesleyan.edu).

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

TH14			15min5:15

EFFECTS OF A REMOTE BINDING PARTNER ON THE ELECTRIC FIELD AND ELECTRIC FIELD GRADIENT AT AN ATOM IN A WEAKLY BOUND TRIMER: MICROWAVE SPECTROSCOPY AND QUANTUM MECHANICAL COMPUTATIONS ON Kr-SO₃ AND Kr-SO₃-CO.

REBECCA B. MACKENZIE, BROOKE A. TIMP, KENNETH R. LEOPOLD, Department of Chemistry, University of Minnesota, 207 Pleasant St., SE, Minneapolis, MN 55455; YIRONG MO, Department of Chemistry, Western Michigan University, Kalamazoo, MI 49008.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

TH15			15min5:32

MICROWAVE SPECTRUM AND STRUCTURE OF THE 2,6-DIFLUOROPYRIDINE-CO₂ COMPLEX.

CHRISTOPHER T. DEWBERRY, Department of Chemistry, University of Minnesota, 207 Pleasant St., SE, Minneapolis, MN 55455; JESSICA L. MUELLER, MARK D. MARSHALL, HELEN O. LEUNG, Department of Chemistry, Amherst College, P.O. Box 5000, Amherst, MA 01002-5000; KENNETH R. LEOPOLD, Department of Chemistry, University of Minnesota, 207 Pleasant St., SE, Minneapolis, MN 55455.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

TH16			15min5:49

OBSERVATION OF A MODERATE STRENGTH INTERACTION OF HYDROGEN WITH A COINAGE METAL HALIDE: THE ROTATIONAL SPECTRUM AND STRUCTURE OF THE p -H₂-CuCl AND o -H₂-CuCl COMPLEXES.

HERBERT M. PICKETT, DANIEL A. OBENCHAIN, G. S. GRUBBS II AND STEWART E. NOVICK, Department of Chemistry, Wesleyan University, 52 Lawn Avenue, Middletown, CT, 06459-0180, USA .

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]