10min:
DIFFERENT POLARIZED COMPONENTS SHAPE OF RAMAN 1343 CM-1 BAND FOR NITRO-BENZENE AND ITS SOLUTIONS.

F. H. TUKHVATULLIN, A. JUMABOEV, U. N. TASHKENBAEV, S. A. OSMANOV, Z. MAMATOV, H. A. HUSHVAKTOV, Samarkand State University, 703004 Samarkand, Uzbekistan.

In Raman spectra for 1343 cm-1 band of liquid nitro-benzene the maxima position of perpendicular and parallel polarized components are differed on =1,8 cm-1. At dilution of nitro-benzene in hexane (within the limits of solubility), chloroform and nitro-methane the frequency difference is decreased and is reduced to zero at the strong dilution. Peculiar kind of dependence the as a function of concentration for mixtures nitro-benzene with nitro-methane is associated with large dipole moment of solvent molecules.