15min:

LISA M. GOSS, Department of Chemistry, Idaho State University, Campus Box 8023, Pocatello ID, 83209; THOMAS A. BLAKE, Pacific Northwest National Laboratory, P. O. Box 999, Mail Stop K8-88, Richland, WA 99352.

The infrared spectrum of gas phase methyl nitrite (CH₃ONO) has been recorded at high resolution between 600 and 4000 cm^-1. Methyl nitrite contains a mixture of cis and trans rotational isomers which are interconverted by the N=O torsion. As in the ₈ vibration of the cis form, the ₉ vibration is not too congested, consistent with the high barrier to rotation of the methyl group in the cis form. The ₉, with an origin at 627.9 cm ^-1, has been assigned by previous workers to the ONO bend of the cis conformer and several hot bands are also present in this region. In this study, a spectrum taken at 0.0015 cm ^-1 resolution on the PNNL IFS120/HR in a 20 cm cell was used to assign more than 500 A-type transitions of the cis ₉ between 600 and 650 cm ^-1 and a set of excited state constants was determined.