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GEORGES WLODARCZAK, JEAN-MARCEL COLMONT AND FRANCOIS ROHART, Laboratoire de Physique des Lasers, Atomes et Molécules, UMR CNRS 8523, Université de Lille 1, 59655 Villeneuve d'Ascq, France; LINH NGUYEN AND JEANNA BULDYREVA, Laboratoire de Physique Moléculaire, UMR CNRS 6624, Université de Franche-Comté, 16 route de Gray, 25030 Besançon cedex, France.
The exhaustive study of N2O/N2 (O2, air) rotational transtitions situated in the sub-millimeter wave domain is of a fundamental importance for the reliable interpretation of the experimental data collected by the satellite ODIN (the Swedish-led satellite project supported by Canada, Finland and France). In complement to our recent laboratory measurements near 201, 552 and 577 GHz [1], new results are obtained with a frequency-modulated spectrometer for the N2O transitions at 502.3 and 602 GHz. The theoretical computations for the collisional line broadening are based on a semiclassical formalism with exact trajectories [2]. The analysis of the line profile is performed with both the classical Voigt model and a speed-dependent Voigt model.
\lbrack1\rbrack F.~Rohart, J.-M.~Colmont, G.~Wlodarczak, and J.-P.~Bouanich, J. Mol. Spectrosc. 222, 159-171 (2003).
\lbrack2\rbrack J.~Buldyreva, J.~Bonamy, D.~Robert, J. Quant. Spectrosc. Radiat. Transf. 62, 321-343 (1999).