			15min:

HIGH ORDER CORRECTIONS TO ROTATIONAL CONSTANTS BY VIBRATION-ROTATION PERTURBATION THEORY.

JUANA VÁZQUEZ AND JOHN F. STANTON, Institute for Theoretical Chemistry, Department of Chemistry, University of Texas, Austin,Tx 78721.

Vibrational corrections to rotational constants due to second vibration-rotation interaction constants, i.e. gamma ^ alpha _ij, are presented under the framework of fourth order Rayleigh-Schödinger perturbation theory. Applications to some asymmetric top molecules are analyzed and compared with corrections resulting from the first vibration-rotation constants, alpha ^ alpha _i.