15min:

MICHAEL C. MCCARTHY AND PATRICK THADDEUS, Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138, and School of Engineering & Applied Sciences, Harvard University, 29 Oxford St., Cambridge, MA 02138.

The rotational spectrum of protonated carbonyl sulfide, HSCO⁺, has now been detected in the centimeter-wave band in a molecular beam by Fourier transform microwave spectroscopy. Rotational and centrifugal distortion constants have been determined from transitions in the K_a=0 ladder of the normal isotopic species, and DSCO⁺ and H³⁴SCO⁺. HSCO⁺ is systematically more abundant by a factor of three than HOCS⁺, the isomer obtained by attaching the H⁺ to the other end of the molecule, which ab initio calculations long predicted to be higher in energy by 4-5 kcal/mol.

In addition, the rotational spectra of several other protonated species such as DCS⁺ and NNOH⁺, and complexes such as Ar-D₃⁺, Ar-DCO⁺, Ar-N₂H⁺, etc. have been detected at somewhat higher spectral resolution than previously reported. These new measurements either better resolve or reveal additional line structure which is not observed in the lower resolution studies.