15min:
HYDROCARBON RADICALS ISOLATED IN HELIUM NANODROPLETS.

ALEXANDER M. MORRISON, STEVEN D. FLYNN, TAO LIANG AND GARY E. DOUBERLY, Department of Chemistry, University of Georgia, Athens, Georgia 30602.

We report high resolution infrared spectra in the C-H stretch region for small hydrocarbon radicals isolated in helium nanodroplets. Stark Spectroscopy of the symmetric CH2 stretch of the ethyl radical provides the first experimentally measured dipole moment for this species.