15min:

M. P. ZIEMKIEWICZ, A. ZUTZ AND D. J. NESBITT, JILA, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado, USA.

Room temperature ionic liquids (RTIL’s) are a highly diverse class of materials with many potential technological applications. They are candidates for use in advanced electrolytes, green solvents, and supported liquid membranes for CO₂ sequestration. We present studies where inelastic scattering of high or low velocity nitric oxide provides insight into the microscopic structure of these complex surfaces. As an open shell diatomic, jet-cooled NO [² _1/2(J = 0.5)] features both molecular and electronic collision dynamics as seen by probing scattered rotational and spin-orbit distributions respectively. These studies show substantial variation in degree of rotational and electronic excitation as ionic liquid identity is varied. Also, surface heating is found to have a strong effect on scattered spin-orbit branching, possibly due to the dependence of surface structure on temperature. This is discussed in terms of a picture where the electronic degree of freedom may serve as a sensitive measure of the cationic versus anionic nature of the top few layers of this material.