Mail:
Dept. of Chemistry
Ohio State University
100 W. 18th Ave.
Columbus, OH 43210
Office:
412 CBEC
Email:
herbert@
chemistry.ohio-state.edu
Adiabatic rigid body diffusion Monte Carlo techniques are used to investigate the structure and spectroscopy of complexes of one to four neon atoms with SH (Ã 2Σ+) While these systems contain multiple low-lying minima, the ground state wave functions are well described by a neon cluster weakly interacting with SH. This structure persists in low-lying excited states, in the case of complexes of two neon atoms with SH or SD.